• ASTM D 6338 : 2017

    Current The latest, up-to-date edition.

    Standard Classification System for Highly Crosslinked Thermoplastic Vulcanizates (HCTPV) Based on ASTM Standard Test Methods

    Available format(s):  Hardcopy, PDF

    Language(s):  English

    Published date:  01-08-2017

    Publisher:  American Society for Testing and Materials

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    1.1This classification system covers highly crosslinked thermoplastic vulcanizates (HCTPV) for extrusion, molding and other fabrication methods. Highly crosslinked thermoplastic vulcanizates (HCTPV) are thermoplastic elastomers (TPE) consisting of two or more polymer systems at least one of which is rubbery and highly (>95 %) crosslinked and at least one of which is thermoplastic, with each system having its own phase. The thermoplastic phase will tend to be continuous and the rubbery phase discontinuous. The high level of crosslinking and ultrafine particle size (ca 1 μm diameter) of the rubbery phase give rise to properties more closely approaching those of conventional thermoset rubber, when compared to the same thermoplastic/rubbery polymer composition with a lower level (95 %) of crosslinking. The HCTPV polymer compositions may contain fillers, reinforcing agents, plasticizers, resins, antidegradants, colorants and other beneficial constituents. Recycled HCTPV are not covered in this classification system.

    1.2The properties included in this standard are those required to identify the compositions covered. Other requirements necessary to identify particular characteristics important to specialized applications are to be specified by using suffixes as given in Section 5.

    1.3This classification system and subsequent line callout (specification) are intended to provide a means of calling out plastic materials used in the fabrication of end items or parts. It is not intended for the selection of materials. Material selection can be made by those having expertise in the plastic field only after careful consideration of the design and the performance required of the part, the environment to which it will be exposed, the fabrication process to be employed, the costs involved, and the inherent properties of the material other than those covered by this standard.

    1.4As given in IEEE/ASTM SI-10, values in SI units are to be regarded as standard.

    Note 1:There is no known ISO equivalent to this standard.

    1.5This standard is based on testing completed in accordance with ASTM standard test methods.

    1.6The following safety hazards caveat pertains only to the test methods portion, Section 11, of this classification system. This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health and environmental practices and determine the applicability of regulatory limitations prior to use.

    1.7This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

    General Product Information - (Show below) - (Hide below)

    Committee D 20
    Document Type Standard
    Publisher American Society for Testing and Materials
    Status Current
    Supersedes

    Standards Referenced By This Book - (Show below) - (Hide below)

    ASTM D 6924 : 2003 : R2017 Standard Specification for Preformed Thermoplastic Vulcanizate Elastomeric Joint Seals for Bridges
    ASTM D 4000 : 2016 Standard Classification System for Specifying Plastic Materials

    Standards Referencing This Book - (Show below) - (Hide below)

    ASTM D 1566 : 2004 : REV A Standard Terminology Relating to Rubber
    ASTM D 2240 : 2000 Standard Test Method for Rubber Property—Durometer Hardness
    ASTM D 3182 : 2015 Standard Practice for Rubber—Materials, Equipment, and Procedures for Mixing Standard Compounds and Preparing Standard Vulcanized Sheets
    ASTM D 471 : 2016 : REV A Standard Test Method for Rubber Property—Effect of Liquids
    ASTM D 1566 : 2009 Standard Terminology Relating to Rubber
    ASTM D 883 : 2023 Standard Terminology Relating to Plastics
    ASTM D 1566 : 2006 Standard Terminology Relating to Rubber
    ASTM D 1566 : 2008 : REV A Standard Terminology Relating to Rubber
    ASTM D 1566 : 2021 : REV A Standard Terminology Relating to Rubber
    ASTM D 4000 : 2013 Standard Classification System for Specifying Plastic Materials
    ASTM E 29 : 2013 : R2019 Standard Practice for Using Significant Digits in Test Data to Determine Conformance with Specifications
    ASTM D 3892 : 2015 : R2020 Standard Practice for Packaging/Packing of Plastics
    ASTM D 1434 : 1982 : R2003 Standard Test Method for Determining Gas Permeability Characteristics of Plastic Film and Sheeting
    ASTM D 3182 : 2007 : R2012 Standard Practice for Rubber—Materials, Equipment, and Procedures for Mixing Standard Compounds and Preparing Standard Vulcanized Sheets
    ASTM D 1566 : 2005 Standard Terminology Relating to Rubber
    ASTM D 4000 : 2003 : REV A Standard Classification System for Specifying Plastic Materials
    ASTM D 4000 : 2000 : REV A Standard Classification System for Specifying Plastic Materials
    ASTM D 883 : 2024 Standard Terminology Relating to Plastics
    ASTM D 4000 : 2012 Standard Classification System for Specifying Plastic Materials
    ASTM D 1566 : 2002 : REV A Standard Terminology Relating to Rubber
    ASTM D 4000 : 2009 Standard Classification System for Specifying Plastic Materials
    ASTM E 29 : 2002 Standard Practice for Using Significant Digits in Test Data to Determine Conformance with Specifications
    ASTM D 3892 : 1993 : R2003 Standard Practice for Packaging/Packing of Plastics
    ASTM D 3892 : 2015 Standard Practice for Packaging/Packing of Plastics
    ASTM D 1566 : 2007 Standard Terminology Relating to Rubber
    ASTM D 3182 : 1989 : R2006 Standard Practice for Rubber-Materials, Equipment, and Procedures for Mixing Standard Compounds and Preparing Standard Vulcanized Sheets
    ASTM D 1566 : 2019 Standard Terminology Relating to Rubber
    ASTM D 2240 : 2004 Standard Test Method for Rubber Property—Durometer Hardness
    ASTM D 1566 : 2015 Standard Terminology Relating to Rubber
    ASTM D 4000 : 2011 Standard Classification System for Specifying Plastic Materials
    ASTM D 883 : 2022 Standard Terminology Relating to Plastics
    ASTM D 883 : 2020 : REV B Standard Terminology Relating to Plastics
    ASTM D 1566 : 2008 Standard Terminology Relating to Rubber
    ASTM D 3892 : 1993 : R1998 Standard Practice for Packaging/Packing of Plastics
    ASTM D 3182 : 1989 : R2001 : EDT 1 Standard Practice for Rubber-Materials, Equipment, and Procedures for Mixing Standard Compounds and Preparing Standard Vulcanized Sheets
    ASTM D 1566 : 2005 : REV A Standard Terminology Relating to Rubber
    ASTM D 412 : 2016 : EDT 1 Standard Test Methods for Vulcanized Rubber and Thermoplastic Elastomers—Tension
    ASTM D 4000 : 2004 : EDT 1 Standard Classification System for Specifying Plastic Materials
    ASTM D 4000 : 2023 Standard Classification System for Specifying Plastic Materials
    ASTM D 2240 : 2004 : EDT 1 Standard Test Method for Rubber Property—Durometer Hardness
    ASTM D 1566 : 2006 : REV A Standard Terminology Relating to Rubber
    ASTM D 1566 : 2003 : REV A Standard Terminology Relating to Rubber
    ASTM D 471 : 2016 : REV A : R2021 Standard Test Method for Rubber Property—Effect of Liquids
    ASTM D 4000 : 2009 : REV B Standard Classification System for Specifying Plastic Materials
    ASTM D 4000 : 2000 Standard Classification System for Specifying Plastic Materials
    ASTM D 1566 : 2006 : REV B Standard Terminology Relating to Rubber
    ASTM D 4000 : 2010 : REV A Standard Classification System for Specifying Plastic Materials
    ASTM D 412 : 2016 Standard Test Methods for Vulcanized Rubber and Thermoplastic Elastomers—Tension
    ASTM D 4000 : 2007 Standard Classification System for Specifying Plastic Materials
    ASTM D 1566 : 2005 : REV B Standard Terminology Relating to Rubber
    ASTM D 4000 : 2009 : REV A Standard Classification System for Specifying Plastic Materials
    ASTM D 4000 : 2001 Standard Classification System for Specifying Plastic Materials
    ASTM D 3182 : 2007 Standard Practice for Rubber-Materials, Equipment, and Procedures for Mixing Standard Compounds and Preparing Standard Vulcanized Sheets
    ASTM D 1566 : 2011 Standard Terminology Relating to Rubber
    ASTM D 4000 : 2008 Standard Classification System for Specifying Plastic Materials
    ASTM D 638 : 2014 Standard Test Method for Tensile Properties of Plastics
    ASTM D 2240 : 2015 : R2021 Standard Test Method for Rubber Property—Durometer Hardness
    ASTM D 1566 : 2021 Standard Terminology Relating to Rubber
    ASTM D 1566 : 2000 : REV B Standard Terminology Relating to Rubber
    ASTM D 2240 : 2002 Standard Test Method for Rubber Property—Durometer Hardness
    ASTM D 6869 : 2017 Standard Test Method for Coulometric and Volumetric Determination of Moisture in Plastics Using the Karl Fischer Reaction (the Reaction of Iodine with Water)
    ASTM D 1566 : 2014 Standard Terminology Relating to Rubber
    ASTM D 6869 : 2003 : R2011 Standard Test Method for Coulometric and Volumetric Determination of Moisture in Plastics Using the Karl Fischer Reaction (the Reaction of Iodine with Water)
    ASTM D 1434 : 1982 : R2015 : EDT 1 Standard Test Method for Determining Gas Permeability Characteristics of Plastic Film and Sheeting
    ASTM D 618 : 2013 Standard Practice for Conditioning Plastics for Testing
    ASTM D 2240 : 2015 Standard Test Method for Rubber Property—Durometer Hardness
    ASTM D 2240 : 2003 Standard Test Method for Rubber Property—Durometer Hardness
    ASTM D 4000 : 2001 : REV A : EDT 1 Standard Classification System for Specifying Plastic Materials
    ASTM D 1566 : 2010 Standard Terminology Relating to Rubber
    ASTM D 4000 : 2004 Standard Classification System for Specifying Plastic Materials
    ASTM D 2240 : 2002 : REV B Standard Test Method for Rubber Property—Durometer Hardness
    ASTM D 1434 : 1982 : R2009 : EDT 1 Standard Test Method for Determining Gas Permeability Characteristics of Plastic Film and Sheeting
    ASTM D 3182 : 1989 : R2001 Standard Practice for Rubber—Materials, Equipment, and Procedures for Mixing Standard Compounds and Preparing Standard Vulcanized Sheets
    ASTM D 2240 : 2015 : EDT 1 Standard Test Method for Rubber Property—Durometer Hardness
    ASTM D 1566 : 2003 Standard Terminology Relating to Rubber
    ASTM D 412 : 2016 : R2021 Standard Test Methods for Vulcanized Rubber and Thermoplastic Elastomers—Tension
    ASTM D 3892 : 1993 : R2009 Standard Practice for Packaging/Packing of Plastics
    ASTM D 3182 : 2021 Standard Practice for Rubber—Materials, Equipment, and Procedures for Mixing Standard Compounds and Preparing Standard Vulcanized Sheets
    ASTM D 4000 : 2010 Standard Classification System for Specifying Plastic Materials
    ASTM D 1566 : 2000 Standard Terminology Relating to Rubber
    ASTM D 2240 : 2005 Standard Test Method for Rubber Property—Durometer Hardness
    ASTM D 3182 : 1989 : R1994 Standard Practice for Rubber—Materials, Equipment, and Procedures for Mixing Standard Compounds and Preparing Standard Vulcanized Sheets
    ASTM D 1434 : 2023 Standard Test Method for Determining Gas Permeability Characteristics of Plastic Film and Sheeting
    ASTM D 2240 : 2005 : R2010 Standard Test Method for Rubber Property—Durometer Hardness
    ASTM D 1566 : 2020 Standard Terminology Relating to Rubber
    ASTM D 3182 : 2016 Standard Practice for Rubber—Materials, Equipment, and Procedures for Mixing Standard Compounds and Preparing Standard Vulcanized Sheets
    ASTM D 1566 : 2007 : REV A Standard Terminology Relating to Rubber
    ASTM D 3182 : 2021 : REV A Standard Practice for Rubber—Materials, Equipment, and Procedures for Mixing Standard Compounds and Preparing Standard Vulcanized Sheets
    ASTM D 1566 : 2005 : REV C Standard Terminology Relating to Rubber
    ASTM D 4000 : 2003 Standard Classification System for Specifying Plastic Materials
    ASTM D 2240 : 2002 : REV A Standard Test Method for Rubber Property—Durometer Hardness
    ASTM D 4000 : 2020 Standard Classification System for Specifying Plastic Materials
    ASTM D 1566 : 2010 : EDT 1 Standard Terminology Relating to Rubber
    ASTM D 6869 : 2003 Standard Test Method for Coulometric and Volumetric Determination of Moisture in Plastics Using the Karl Fischer Reaction (the Reaction of Iodine with Water)
    ASTM D 618 : 2021 Standard Practice for Conditioning Plastics for Testing
    ASTM D 1434 : 1982 : R1998 Standard Test Method for Determining Gas Permeability Characteristics of Plastic Film and Sheeting
    ASTM D 638 : 2022 Standard Test Method for Tensile Properties of Plastics
    ASTM D 3182 : 2015 : REV A Standard Practice for Rubber—Materials, Equipment, and Procedures for Mixing Standard Compounds and Preparing Standard Vulcanized Sheets
    ASTM D 1566 : 2008 : REV B Standard Terminology Relating to Rubber
    ASTM E 29 : 2022 Standard Practice for Using Significant Digits in Test Data to Determine Conformance with Specifications
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