ASTM D 974 : 2014 : EDT 2
Superseded
A superseded Standard is one, which is fully replaced by another Standard, which is a new edition of the same Standard.
View Superseded by
Standard Test Method for Acid and Base Number by Color-Indicator Titration
Hardcopy , PDF
10-05-2023
English
26-02-2016
Committee |
D 02
|
DocumentType |
Test Method
|
Pages |
7
|
PublisherName |
American Society for Testing and Materials
|
Status |
Superseded
|
SupersededBy | |
Supersedes |
1.1This test method covers the determination of acidic or basic constituents (Note 1) in petroleum products2 and lubricants soluble or nearly soluble in mixtures of toluene and isopropyl alcohol. It is applicable for the determination of acids or bases whose dissociation constants in water are larger than 10−9; extremely weak acids or bases whose dissociation constants are smaller than 10−9 do not interfere. Salts react if their hydrolysis constants are larger than 10−9.
Note 1:In new and used oils, the constituents considered to have acidic characteristics include organic and inorganic acids, esters, phenolic compounds, lactones, resins, salts of heavy metals, and addition agents such as inhibitors and detergents. Similarly, constituents considered to have basic properties include organic and inorganic bases, amino compounds, salts of weak acids (soaps), basic salts of polyacidic bases, salts of heavy metals, and addition agents such as inhibitors and detergents.
Note 2:This test method is not suitable for measuring the basic constituents of many basic additive-type lubricating oils. Test Method D4739 can be used for this purpose.
1.2This test method can be used to indicate relative changes that occur in an oil during use under oxidizing conditions. Although the titration is made under definite equilibrium conditions, the method does not measure an absolute acidic or basic property that can be used to predict performance of an oil under service conditions. No general relationship between bearing corrosion and acid or base numbers is known.
Note 3:Oils, such as many cutting oils, rustproofing oils, and similar compounded oils, or excessively dark-colored oils, that cannot be analyzed for acid number by this test method due to obscurity of the color-indicator end point, can be analyzed by Test Method D664. The acid numbers obtained by this color-indicator test method need not be numerically the same as those obtained by Test Method D664, the base numbers obtained by this color indicator test method need not be numerically the same as those obtained by Test Method D4739, but they are generally of the same order of magnitude.
1.3The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
1.4This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.
ASTM D 4304 : 2022 | Standard Specification for Mineral and Synthetic Lubricating Oil Used in Steam or Gas Turbines |
ASTM D 7414 : 2022 | Standard Test Method for Condition Monitoring of Oxidation in In-Service Petroleum and Hydrocarbon Based Lubricants by Trend Analysis Using Fourier Transform Infrared (FT-IR) Spectrometry |
ASTM D 6224 : 2022 | Standard Practice for In-Service Monitoring of Lubricating Oil for Auxiliary Power Plant Equipment |
ASTM D 6074 : 2015 : R2022 | Standard Guide for Characterizing Hydrocarbon Lubricant Base Oils |
ASTM D 4378 : 2022 | Standard Practice for In-Service Monitoring of Mineral Turbine Oils for Steam, Gas, and Combined Cycle Turbines |
ASTM D 3394 : 2016 : R2022 | Standard Test Methods for Sampling and Testing Electrical Insulating Board |
ASTM D 7415 : 2022 | Standard Test Method for Condition Monitoring of Sulfate By-Products in In-Service Petroleum and Hydrocarbon Based Lubricants by Trend Analysis Using Fourier Transform Infrared (FT-IR) Spectrometry |
ASTM D 6823 : 2008 : R2021 | Standard Specification for Commercial Boiler Fuels With Used Lubricating Oils |
ASTM D 6710 : 2021 | Standard Guide for Evaluation of Hydrocarbon-Based Quench Oil |
ASTM D 5222 : 2023 | Standard Specification for Less Flammable High Molecular Weight Hydrocarbon Mineral Electrical Insulating Liquids |
ASTM D 8240 : 2022 : EDT 1 | Standard Specification for Less-Flammable Synthetic Ester Liquids Used in Electrical Apparatus |
ASTM D 8045 : 2017 : R2023 | Standard Test Method for Acid Number of Crude Oils and Petroleum Products by Catalytic Thermometric Titration |
ASTM D 8180 : 2023 | Standard Specification for Rerefined Mineral Insulating Liquid Used in Electrical Apparatus |
ASTM D 3339 : 2021 | Standard Test Method for Acid Number of Petroleum Products by Semi-Micro Color Indicator Titration |
ASTM D 4293 : 2022 | Standard Specification for Phosphate Ester-Based Fluids for Turbine Lubrication and Steam Turbine Electro-Hydraulic Control (EHC) Applications |
ASTM D 117 : 2022 | Standard Guide for Sampling, Test Methods, and Specifications for Electrical Insulating Liquids |
ASTM D 2440 : 2013 : R2021 | Standard Test Method for Oxidation Stability of Mineral Insulating Oil |
ASTM D 7720 : 2021 | Standard Guide for Statistically Evaluating Measurand Alarm Limits when Using Oil Analysis to Monitor Equipment and Oil for Fitness and Contamination |
ASTM D 2226 : 1993 : R2022 | Standard Classification for Various Types of Petroleum Oils for Rubber Compounding Use |
ASTM D 4871 : 2011 : R2022 | Standard Guide for Universal Oxidation/Thermal Stability Test Apparatus |
ASTM D 4174 : 2017 | Standard Practice for Cleaning, Flushing, and Purification of Petroleum Fluid Hydraulic Systems |
ASTM D 6514 : 2003 : R2019 : EDT 1 | Standard Test Method for High Temperature Universal Oxidation Test for Turbine Oils |
ASTM D 8045 : 2017 : EDT 1 | Standard Test Method for Acid Number of Crude Oils and Petroleum Products by Catalytic Thermometric Titration |
ASTM D 8032 : 2020 | Standard Test Method for Acid Number of Terephthalic Acid by Color-Indicator Titration |
ASTM D 5846 : 2007 : R2017 | Standard Test Method for Universal Oxidation Test for Hydraulic and Turbine Oils Using the Universal Oxidation Test Apparatus |
ASTM D 8181 : 2019 | Standard Specification for Microemulsion Blendstock for Preparing Microemulsion Test Fuel Oils |
ASTM D 6751 : 2020 : REV A | Standard Specification for Biodiesel Fuel Blend Stock (B100) for Middle Distillate Fuels |
ASTM D 7666 : 2012 : R2019 | Standard Specification for Triglyceride Burner Fuel |
ASTM D 5282 : 2005 : R2020 | Standard Test Methods for Compatibility of Construction Material with Silicone Fluid Used for Electrical Insulation |
ASTM D 5222 : 2016 | Standard Specification for High Fire-Point Mineral Electrical Insulating Oils |
ASTM D 4304 : 2017 | Standard Specification for Mineral and Synthetic Lubricating Oil Used in Steam or Gas Turbines |
ASTM D 664 : 2018 : EDT 2 | Standard Test Method for Acid Number of Petroleum Products by Potentiometric Titration |
ASTM D 3455 : 2011 : R2019 | Standard Test Methods for Compatibility of Construction Material with Electrical Insulating Oil of Petroleum Origin |
ASTM D 3339 : 2012 : R2017 | Standard Test Method for Acid Number of Petroleum Products by Semi-Micro Color Indicator Titration |
ASTM D 2440 : 2013 | Standard Test Method for Oxidation Stability of Mineral Insulating Oil |
ASTM D 6224 : 2016 | Standard Practice for In-Service Monitoring of Lubricating Oil for Auxiliary Power Plant Equipment |
ASTM D 117 : 2018 | Standard Guide for Sampling, Test Methods, and Specifications for Electrical Insulating Liquids |
ASTM D 1934 : 2020 | Standard Test Method for Oxidative Aging of Electrical Insulating Liquids by Open-Beaker Method |
ASTM D 7044 : 2015 | Standard Specification for Biodegradable Fire Resistant Hydraulic Fluids (Withdrawn 2024) |
ASTM D 6469 : 2020 | Standard Guide for Microbial Contamination in Fuels and Fuel Systems |
ASTM D 3487 : 2016 : EDT 1 | Standard Specification for Mineral Insulating Oil Used in Electrical Apparatus |
ASTM D 6439 : 2011 : R2017 | Standard Guide for Cleaning, Flushing, and Purification of Steam, Gas, and Hydroelectric Turbine Lubrication Systems |
ASTM D 2619 : 2021 | Standard Test Method for Hydrolytic Stability of Hydraulic Fluids (Beverage Bottle Method) |
ASTM D 4871 : 2011 : R2016 | Standard Guide for Universal Oxidation/Thermal Stability Test Apparatus |
ASTM D 5770 : 2011 : R2017 | Standard Test Method for Semiquantitative Micro Determination of Acid Number of Lubricating Oils During Oxidation Testing |
ASTM D 7752 : 2018 | Standard Practice for Evaluating Compatibility of Mixtures of Hydraulic Fluids |
ASTM D 7414 : 2018 | Standard Test Method for Condition Monitoring of Oxidation in In-Service Petroleum and Hydrocarbon Based Lubricants by Trend Analysis Using Fourier Transform Infrared (FT-IR) Spectrometry |
ASTM D 3394 : 2016 | Standard Test Methods for Sampling and Testing Electrical Insulating Board |
ASTM D 6823 : 2008 : R2013 | Standard Specification for Commercial Boiler Fuels With Used Lubricating Oils |
ASTM D 7720 : 2011 : R2017 | Standard Guide for Statistically Evaluating Measurand Alarm Limits when Using Oil Analysis to Monitor Equipment and Oil for Fitness and Contamination |
ASTM D 6871 : 2017 | Standard Specification for Natural (Vegetable Oil) Ester Fluids Used in Electrical Apparatus |
ASTM D 6074 : 2015 | Standard Guide for Characterizing Hydrocarbon Lubricant Base Oils |
ASTM D 7415 : 2018 | Standard Test Method for Condition Monitoring of Sulfate By-Products in In-Service Petroleum and Hydrocarbon Based Lubricants by Trend Analysis Using Fourier Transform Infrared (FT-IR) Spectrometry |
ASTM D 8029 : 2018 | Standard Specification for Biodegradable, Low Aquatic Toxicity Hydraulic Fluids |
ASTM D 2225 : 2020 | Standard Test Methods for Silicone Liquids Used for Electrical Insulation |
ASTM F 2161 : 2021 | Standard Guide for Instrument and Precision Bearing Lubricants—Part 1 Oils |
ASTM D 1534 : 1995 : R2017 | Standard Test Method for Approximate Acidity in Electrical Insulating Liquids by Color-Indicator Titration |
ASTM D 7155 : 2020 | Standard Practice for Evaluating Compatibility of Mixtures of Turbine Lubricating Oils |
ASTM D 2226 : 1993 : R2018 | Standard Classification for Various Types of Petroleum Oils for Rubber Compounding Use |
ASTM D 8324 : 2021 | Standard Guide for Selection of Environmentally Acceptable Lubricants for the U.S. Environmental Protection Agency (EPA) Vessel General Permit |
ASTM D 4652 : 2020 | Standard Specification for Silicone Liquid Used for Electrical Insulation |
ASTM D 6710 : 2017 | Standard Guide for Evaluation of Hydrocarbon-Based Quench Oil |
ASTM D 4293 : 2015 : EDT 1 | Standard Specification for Phosphate Ester Based Fluids for Turbine Lubrication and Steam Turbine Electro-Hydraulic Control (EHC) Applications |
ASTM D 4378 : 2020 | Standard Practice for In-Service Monitoring of Mineral Turbine Oils for Steam, Gas, and Combined Cycle Turbines |
ASTM D 6158 : 2018 | Standard Specification for Mineral Hydraulic Oils |
ASTM D 4175 : 2020 | Standard Terminology Relating to Petroleum Products, Liquid Fuels, and Lubricants |
ASTM D 4175 : 2014 | Standard Terminology Relating to Petroleum, Petroleum Products, and Lubricants |
ASTM D 4175 : 2009 : REV A : EDT 1 | Standard Terminology Relating to Petroleum, Petroleum Products, and Lubricants |
ASTM D 4175 : 2008 : REV B : EDT 1 | Standard Terminology Relating to Petroleum, Petroleum Products, and Lubricants |
ASTM D 4175 : 2005 | Standard Terminology Relating to Petroleum, Petroleum Products, and Lubricants |
ASTM D 4175 : 2005 : EDT 2 | Standard Terminology Relating to Petroleum, Petroleum Products, and Lubricants |
ASTM D 4175 : 2015 : REV C | Standard Terminology Relating to Petroleum, Petroleum Products, and Lubricants |
ASTM D 4175 : 2017 : REV A : EDT 1 | Standard Terminology Relating to Petroleum Products, Liquid Fuels, and Lubricants |
ASTM D 4739 : 2005 | Standard Test Method for Base Number Determination by Potentiometric Titration |
ASTM D 4175 : 2008 : REV A | Standard Terminology Relating to Petroleum, Petroleum Products, and Lubricants |
ASTM D 4175 : 2020 : REV A | Standard Terminology Relating to Petroleum Products, Liquid Fuels, and Lubricants |
ASTM D 4175 : 2017 : REV B | Standard Terminology Relating to Petroleum Products, Liquid Fuels, and Lubricants |
ASTM D 4175 : 2009 | Standard Terminology Relating to Petroleum, Petroleum Products, and Lubricants |
ASTM D 1193 : 1977 : R1983 : EDT 1 | Standard Specification for Reagent Water |
ASTM D 4175 : 2009 : REV A : EDT 4 | Standard Terminology Relating to Petroleum, Petroleum Products, and Lubricants |
ASTM D 4175 : 2009 : REV A : EDT 3 | Standard Terminology Relating to Petroleum, Petroleum Products, and Lubricants |
ASTM D 4175 : 2018 | Standard Terminology Relating to Petroleum Products, Liquid Fuels, and Lubricants |
ASTM D 4175 : 2001 : EDT 1 | Standard Terminology Relating to Petroleum, Petroleum Products, and Lubricants |
ASTM D 4175 : 2001 | Standard Terminology Relating to Petroleum, Petroleum Products, and Lubricants |
ASTM D 4175 : 2005 : EDT 1 | Standard Terminology Relating to Petroleum, Petroleum Products, and Lubricants |
ASTM D 4739 : 2008 | Standard Test Method for Base Number Determination by Potentiometric Hydrochloric Acid Titration |
ASTM D 4175 : 2002 | Standard Terminology Relating to Petroleum, Petroleum Products, and Lubricants |
ASTM D 4739 : 2017 | Standard Test Method for Base Number Determination by Potentiometric Hydrochloric Acid Titration |
ASTM D 4739 : 2006 | Standard Test Method for Base Number Determination by Potentiometric Titration |
ASTM D 4175 : 2015 | Standard Terminology Relating to Petroleum, Petroleum Products, and Lubricants |
ASTM D 1193 : 2006 : R2011 | Standard Specification for Reagent Water |
ASTM D 4175 : 2002 : REV A : EDT 2 | Standard Terminology Relating to Petroleum, Petroleum Products, and Lubricants |
ASTM D 4739 : 1996 | Standard Test Method for Base Number Determination by Potentiometric Titration |
ASTM D 664 : 1995 | Standard Test Method for Acid Number of Petroleum Products by Potentiometric Titration |
ASTM D 4175 : 2009 : REV A : EDT 5 | Standard Terminology Relating to Petroleum, Petroleum Products, and Lubricants |
ASTM D 4175 : 2016 : REV C | Standard Terminology Relating to Petroleum Products, Liquid Fuels, and Lubricants |
ASTM D 4175 : 2015 : REV B | Standard Terminology Relating to Petroleum, Petroleum Products, and Lubricants |
ASTM D 4175 : 2015 : REV A | Standard Terminology Relating to Petroleum, Petroleum Products, and Lubricants |
ASTM D 4739 : 2011 : R2017 | Standard Test Method for Base Number Determination by Potentiometric Hydrochloric Acid Titration |
ASTM D 1193 : 1991 | Standard Specification for Reagent Water |
ASTM D 4175 : 2009 : REV A | Standard Terminology Relating to Petroleum, Petroleum Products, and Lubricants |
ASTM D 4175 : 2016 : REV B | Standard Terminology Relating to Petroleum Products, Liquid Fuels, and Lubricants |
ASTM D 4175 : 2002 : REV A : EDT 1 | Standard Terminology Relating to Petroleum, Petroleum Products, and Lubricants |
ASTM D 4175 : 2008 | Standard Terminology Relating to Petroleum, Petroleum Products, and Lubricants |
ASTM D 4175 : 2002 : REV A | Standard Terminology Relating to Petroleum, Petroleum Products, and Lubricants |
ASTM D 4175 : 2000 : EDT 1 | Standard Terminology Relating to Petroleum, Petroleum Products, and Lubricants |
ASTM D 4175 : 2016 : REV A | Standard Terminology Relating to Petroleum Products, Liquid Fuels, and Lubricants |
ASTM D 4739 : 2008 : EDT 1 | Standard Test Method for Base Number Determination by Potentiometric Hydrochloric Acid Titration |
ASTM D 4175 : 2019 : EDT 1 | Standard Terminology Relating to Petroleum Products, Liquid Fuels, and Lubricants |
ASTM D 117 : 1996 | Standard Guide for Sampling, Test Methods, Specifications, and Guide for Electrical Insulating Oils of Petroleum Origin |
ASTM D 4175 : 2017 : REV A | Standard Terminology Relating to Petroleum Products, Liquid Fuels, and Lubricants |
ASTM D 4175 : 2009 : REV A : EDT 2 | Standard Terminology Relating to Petroleum, Petroleum Products, and Lubricants |
ASTM D 1193 : 1970 | Standard Specification For Reagent Water |
ASTM D 1193 : 2006 | Standard Specification for Reagent Water |
ASTM D 4175 : 2018 : EDT 1 | Standard Terminology Relating to Petroleum Products, Liquid Fuels, and Lubricants |
ASTM D 4175 : 2016 | Standard Terminology Relating to Petroleum Products, Liquid Fuels, and Lubricants |
ASTM D 1193 : 1999 | Standard Specification for Reagent Water |
ASTM D 4739 : 2011 | Standard Test Method for Base Number Determination by Potentiometric Hydrochloric Acid Titration |
ASTM D 4739 : 2002 | Standard Test Method for Base Number Determination by Potentiometric Titration |
ASTM D 4739 : 2006 : REV A | Standard Test Method for Base Number Determination by Potentiometric Titration |
ASTM D 4175 : 2017 | Standard Terminology Relating to Petroleum Products, Liquid Fuels, and Lubricants |
ASTM D 4175 : 2019 | Standard Terminology Relating to Petroleum Products, Liquid Fuels, and Lubricants |
ASTM D 1193 : 2006 : R2018 | Standard Specification for Reagent Water |
ASTM D 4175 : 2015 : REV B : EDT 1 | Standard Terminology Relating to Petroleum, Petroleum Products, and Lubricants |
ASTM D 4175 : 2008 : REV B | Standard Terminology Relating to Petroleum, Petroleum Products, and Lubricants |
Access your standards online with a subscription
Features
-
Simple online access to standards, technical information and regulations.
-
Critical updates of standards and customisable alerts and notifications.
-
Multi-user online standards collection: secure, flexible and cost effective.